Publications

2021

Insight into the structure–property relationship of UO2 nanoparticles.

Gerber, E., Romanchuk, A. Y., Weiss, S., Bauters, S., Schacherl, B., Vitova, T., Hübner, R., Shams Aldin Azzam, S., Detollenaere, D., Banerjee, D., Butorin, S. M., Kalmykov, S. N., & Kvashnina, K. O, Inorganic Chemistry Frontiers, accepted (2021) https://doi.org/10.1039/D0QI01140A

The application of HEXS and HERFD XANES for accurate structural characterization of actinide nanomaterials: application to ThO₂.

Amidani, L.; Vaughan, G. B. M.; Plakhova, T. V.; Romanchuk, A. Y.; Gerber, E.; Svetogorov, R.; Weiß, S.; Joly, Y.; Kalmykov, S. N.; Kvashnina, K., Chemistry – A European Journal (2020)
DOI: 10.1002/chem.202003360

ROBL-II at ESRF: a synchrotron toolbox for actinide research.

Scheinost, A. C., Claussner, J., Exner, J., Feig, M., Findeisen, S., Hennig, C., Kvashnina, K. O., Naudet, D., Prieur, D., Rossberg, A., Schmidt, M., Qiu, C., Colomp, P., Cohen, C., Dettona, E., Dyadkin, V., & Stumpf, T., Journal of Synchrotron Radiation, 28(1) (2021). https://doi.org/10.1107/S1600577520014265


2020

Nanoscale mechanism of UO2 formation through uranium reduction by magnetite

Pan, Z., Bártová, B., LaGrange, T., Butorin, S. M., Hyatt, N. C., Stennett, M. C., Kvashnina, K. O., & Bernier-Latmani, R., Nature Communications, 11(1), 4001 (2020) https://doi.org/10.1038/s41467-020-17795-0

The effect of Pd(II) chloride complexes anchoring on the formation and properties of Pd/MgAlOx catalysts

Belskaya, O. B.; Zaikovskii, V. I.; Gulyaeva, T. I.; Talsi, V. P.; Trubina, S. V.; Kvashnina, K.; Nizovskii, A. I.; Kalinkin, A. V.; Bukhtiyarov, V. I.; A. Likholobov, V., Journal of Catalysis 392(2020), 108-118
DOI: 10.1016/j.jcat.2020.09.021

Enhanced Sorption of Radionuclides by Defect-Rich Graphene Oxide

Boulanger, N.; Kuzenkova, A. S.; Iakunkov, A.; Romanchuk, A. Y.; Trigub, A. L.; Egorov, A. V.; Bauters, S.; Amidani, L.; Retegan, M.; Kvashnina, K.; Kalmykov, S. N.; Talyzin, A. V., ACS Applied Materials and Interfaces 12(2020)40, 45122-45135
DOI: 10.1021/acsami.0c11122

Synthesis, Structural, and Electronic Properties of K4Pu(VI)O2(CO3)3(cr): An Environmentally Relevant Plutonium Carbonate Complex

Pidchenko, I., März, J., Hunault, M. O. J. Y., Bauters, S., Butorin, S. M., & Kvashnina, K. O., Inorganic Chemistry, 59(17), 11889–11893. (2020) https://doi.org/10.1021/acs.inorgchem.0c01335

The state of trace elements (In, Cu, Ag) in sphalerite studied by X-ray absorption spectroscopy of synthetic minerals

Trofimov, N. D.; Trigub, A. L.; Tagirov, B. R.; Filimonova, O. N.; Evstigneeva, P. V.; Chareev, D. A.; Kvashnina, K.; Nickolsky, M. S., Minerals 10(2020)7, 640
DOI: 10.3390/min10070640

Probing the Local Atomic Structure of In and Cu in Sphalerite by XAS Spectroscopy Enhanced by Reverse Monte Carlo Algorithm

Trigub, A. L., Trofimov, N. D., Tagirov, B. R., Nickolsky, M. S., & Kvashnina, K. O. (2020).., Minerals, 10(10), 841 (2020) https://doi.org/10.3390/min10100841

Fingerprinting mean composition of lithium polysulfide standard solutions by applying high energy resolution fluorescence detected X-ray Absorption Spectroscopy

Robba, A.; Barchasza, C.; Bučar, K.; Petric, M.; Žitnik, M.; Kvashnina, K.; Vaughan, G. B. M.; Bouchet, R.; Alloin, F.; Kavčič, M, J. Phys. Chem. Lett. 11(2020), 5446-5450
DOI: 10.1021/acs.jpclett.0c01120

Size Dependence of Lattice Parameter and Electronic Structure in CeO2 Nanoparticles

Prieur, D.; Bonani, W.; Popa, K.; Walter, O.; Kriegsman, K.; Engelhard, M.; Guo, X.; Eloirdi, R.; Gouder, T.; Beck, A.; Vitova, T.; Scheinost, A.; Kvashnina, K.; Martin, P., Inorganic Chemistry 59(2020)8, 5760-5767
DOI: 10.1021/acs.inorgchem.0c00506

Local Structure in U(IV) and U(V) Environments: The Case of U3O7

Leinders, G.; Bes, R.; Kvashnina, K.; Verwerft, M., Inorganic Chemistry 59(2020)7, 4576-4587
DOI: 10.1021/acs.inorgchem.9b03702

Signatures of Technetium Oxidation States: A New Approach

Bauters, S.; Scheinost, A.; Schmeide, K.; Weiß, S.; Dardenne, K.; Rothe, J.; Mayordomo Herranz, N.; Steudtner, R.; Stumpf, T.; Abram, U.; Butorin, S.; Kvashnina, K., Chemical Communications (2020), 9608-9611
DOI: 10.1039/D0CC03905E

The missing pieces of the PuO2 nanoparticles puzzle

Gerber, E.; Romanchuk, A.; Pidchenko, I.; Amidani, L.; Roßberg, A.; Hennig, C.; Vaughan, G.; Trigub, A.; Egorova, T.; Bauters, S.; Plakhova, T.; Hunault, M.; Weiß, S.; Butorin, S.; Scheinost, A.; Kalmykov, S.; Kvashnina, K., Nanoscale (2020)
DOI: 10.1039/d0nr03767b

A multi-technique study of altered granitic rock from the Krunkelbach Valley uranium deposit, Southern Germany

Pidchenko, I.; Bauters, S.; Sinenko, I.; Hempel, S.; Amidani, L.; Detollenaere, D.; Vinze, L.; Banerjee, D.; Silfhouth, R.; Kalmykov, S.; Göttlicher, J.; Baker, R. J.; Kvashnina, K., RSC Advances 10(2020), 25529-25539
DOI: 10.1039/D0RA03375H

Organic Iron Complexes Enhance Iron Transport Capacity along Estuarine Salinity Gradients

Herzog, S. D.; Kvashnina, K.; Persson, P.; Kritzberg, E., Biogeosciences 17(2020)2, 331-344
DOI: 10.5194/bg-2019-234

Modeling of Nuclear Waste Forms: State-of-the-Art and Perspectives

Kowalski, P. M.; Lange, S.; Deissmann, G.; Sun, M.; Kvashnina, K.; Baker, R.; Kegler, P.; Murphy, G.; Bosbach, D., MRS Advances 5(2020), 213-222
DOI: 10.1557/adv.2020.38

New insights into the mechanism of graphene oxide and radionuclide interaction through vacancy defects

Kuzenkova, A.; Romanchuk, A.; Trigub, A.; Maslakov, K.; Egorov, A.; Amidani, L.; Kittrelle, C.; Kvashnina, K.; Toure, J.; Talyzin, A.; Kalmykov, S., Carbon 158(2020), 291-302
DOI: 10.1016/j.carbon.2019.10.003

2019

Measurement of f orbital hybridization in rare earths through electric dipole-octupole interference in X-ray Absorption Spectroscopy

Juhin, A.; Collins, S. P.; Joly, Y.; Diaz-Lopez, M.; Kvashnina, K.ORC; Glatzel, P.; Brouder, C.; de Groot, F, Physical Review Materials 3(2019), 120801(R)
DOI: 10.1103/PhysRevMaterials.3.120801

The effect of long-range order on intermolecular interactions in organic semiconductors: zinc octaethyl porphyrin molecular thin film model systems.

Kumar, A.; Naumenko, D.; Rossi, G.; Magnano, E.; Nappini, S.; Bondino, F.; Segoloni, E.; Amidani, L.ORC; D’Acapito, F.; Boscherini, F.; Barba, L.; Pace, E.; Benfatto, M.; Casassa, S.; Pedio, M., Physical Chemistry Chemical Physics 21(2019)41, 22966-22975
DOI: 10.1039/c9cp00954j

Eu2+: a suitable substituent for Pb2+ in CsPbX3 perovskite nanocrystals?

Alam, F.; Wegner, K. D.; Pouget, S.; Amidani, L.ORC; Kvashnina, K.; Aldakov, D.; Reiss, P., Journal of Physical Chemistry C 151(2019)23
DOI: 10.1063/1.5126473

A novel metastable pentavalent plutonium solid phase on the pathway from aqueous Pu(VI) to PuO2 nanoparticles

Kvashnina, K.ORC; Romanchuk, A.; Pidchenko, I.; Amidani, L.ORC; Gerber, E.; Trigub, A.; Roßberg, A.; Weiß, S.; Popa, K.; Walter, O.; Caciuffo, R.; Scheinost, A.ORC; Butorin, S.; Kalmykov, S., Angewandte Chemie – International Edition 58(2019)49, 17558-17562
DOI: 10.1002/anie.201911637

Organic Iron Complexes Enhance Iron Transport Capacity along Estuarine Salinity Gradients

Herzog, S. D.; Kvashnina, K.; Persson, P.; Kritzberg, E., Biogeosciences (2019)
DOI: 10.5194/bg-2019-234

Photoelectrocatalytic degradation of emerging contaminants at WO₃/BiVO₄ photoanodes in aqueous solution

Cristino, V.; Pasti, L.; Marchetti, N.; Berardi, S.; Bignozzi, C. A.; Molinari, A.; Passabi, F.; Caramori, S.; Amidani, L.; Orlandi, M.; Bazzanella, N.; Piccioni, A.; Kesavan, J. K.; Boscherini, F.; Pasquini, L., Photochemical & Photobiological Sciences 18(2019)19, 2150-2163
DOI: 10.1039/c9pp00043g

NH₃‑SCR over V−W/TiO₂ Investigated by Operando X‑ray Absorption and Emission Spectroscopy

Doronkin, D. E.; Benzi, F.; Zheng, L.; Sharapa, D. I.; Amidani, L.; Studt, F.; Roesky, P. W.; Casapu, M.; Deutschmann, O.; Grunwaldt, J.-D., Journal of Physical Chemistry C 123(2019), 14338-14349
DOI: 10.1021/acs.jpcc.9b00804

Uncovering the Origin of the Emitting States in Bi³⁺-Activated CaMO₃ (M=Zr, Sn, Ti) Perovskites: Metal-to-Metal Charge Transfer versus s-p Transitions

Back, M.; Ueda, J.; Xu, J.; Asami, K.; Amidani, L.ORC; Trave, E.; Tanabe, S., Journal of Physical Chemistry C 123(2019)23, 14677-14688
DOI: 10.1021/acs.jpcc.9b03940

Size effects in nanocrystalline thoria

Plakhova, T.; Romanchuk, A.; Lykhosherstova, D.; Baranchikov, A.; Dorovatovskii, P.; Svetogorov, R.; Shatalova, T.; Egorova, T.; Trigub, A.; Kvashnina, K.ORC; Ivanov, V.; Kalmykov, S., Journal of Physical Chemistry C 123(2019)37, 23167-23176
DOI: 10.1021/acs.jpcc.9b04379

New insights into the mechanism of graphene oxide and radionuclide interaction through vacancy defects

Kuzenkova, A.; Romanchuk, A.; Trigub, A.; Maslakov, K.; Egorov, A.; Amidani, L.; Kittrelle, C.; Kvashnina, K.ORC; Toure, J.; Talyzin, A.; Kalmykov, S., Carbon (2019)
DOI: 10.1016/j.carbon.2019.10.003

Selective CO2 Electroreduction to Ethylene and Multicarbon Alcohols via Electrolyte-Driven Nanostructuring

Gao, D.; Sinev, I.; Scholten, F.; Arán-Ais, R. M.; Divins, N. J.; Kvashnina, K.; Timoshenko, J.; Roldan Cuenya, B., Angewandte Chemie (2019)
DOI: 10.1002/ange.201910155

Fifteen Years of Radionuclide Research at the KIT Synchrotron Source in the Context of the Nuclear Waste Disposal Safety Case

Rothe, J.; Altmaier, M.; Dagan, R.; Dardenne, K.; Fellhauer, D.; Gaona, X.; González-Robles Corrales, E.; Herm, M.; Kvashnina, K.; Metz, V.; Pidchenko, I.; Schild, D.; Vitova, T.; Geckeis, H., Geosciences 9(2019)2, 91
DOI: 10.3390/geosciences9020091

SiCxNy:Fe films as a tunable ferromagnetic material with tailored conductivity

Pushkarev, R.; Fainer, N.; Kirienko, V.; Matsynin, A.; Nadolinnyy, V.; Merenkov, I.; Trubina, S.; Ehrenburg, S.; Kvashnina, K., Journal of Materials Chemistry C 7(2019), 4250-4258
DOI: 10.1039/C9TC00299E

Understanding the size effects on the electronic structure of ThO2 nanoparticles

Amidani, L.; Plakhova, T. V.; Romanchuk, A. Y.; Gerber, E.; Weiss, S.; Efimenko, A.; Sahle, C. J.; Butorin, S. M.; Kalmykovc, S. N.; Kvashnina, K. O., Physical Chemistry Chemical Physics 21(2019)20, 10635-10643
DOI: 10.1039/C9CP01283D

Application of Layered Double Hydroxides for 99Tc remediation

Daniels, N.; Franzen, C.; Kvashnina, K.; Petrov, V.; Torapava, N.; Bukaemskiy, A.; Kowalski, P.; Hölzer, A.; Walther, C., Applied Clay Science 176(2019), 1-10
DOI: 10.1016/j.clay.2019.04.006

Towards the surface hydroxyl species in CeO2 nanoparticles

Plakhova, T. V.; Romanchuk, A. Y.; Butorin, S. M.; Konyukhova, A. D.; Egorov, A. V.; Shiryaev, A. A.; Baranchikov, A. E.; Dorovatovskii, P. V.; Huthwelker, T.; Gerber, E.; Bauters, S.ORC; Sozarukova, M. M.; Scheinost, A.ORC; Ivanov, V.; Kalmykov, S. N.; Kvashnina, K.ORC, Nanoscale 11(2019), 18142-18149
DOI: 10.1039/C9NR06032D